In order to improve the friction and wear properties, the graphite/CaF2/TiC/Ni-base alloy(GCTN) composite coatings were modified Y2O3 and prepared by plasma spray on the surface of 45 carbon steel. The microstructure, microhardness, fracture toughness and tribological properties of the composite coatings were researched. The results show that the Y2O3 modified GCTN composite coatings are mainly composed of γ-Ni, CrB, Cr7C3, TiC, CaF2 and graphite. Y2O3 reacts with C and produces active element Y by the heat of plasma flame. Y can purify the γ-Ni structure, refine the grain size of CrB and Cr3C7, and improve the density of the composite coating. When Y2O3 is 0.5wt%, the microhardness and fracture toughness of the composite coating are 593.3MPa and 6.82MPa·m1/2 respectively, which are increased by 8% and 22% than those of the composite coating without Y2O3 , because of the refining strengthening effort of CrB and Cr3C7. The improvement of microhardness and fracture toughness of the GCTN-0.5Y2O3 composite coating reduces the adhesive wear and micro fracture wear, so it presents the lowest friction coefficient and wear rate, which are 0.085 and 0.39×10-3mm3/m respectively.